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Volkswagen Golf Mk7 Service & Repair Manual: Charge factor

This page explains the charge factor concept for R134a: as temperature rises, liquid refrigerant expands and the vapour space shrinks — eventually the container could become entirely liquid if overcharged.

There must be space both for liquid and vapour in a container. As the temperature rises, the liquid expands. The space occupied by the vapour becomes smaller. Eventually, there will only be liquid in the container. After that time, even a small increase in temperature will result in a very large increase in pressure, since the liquid is seeking to expand further but there is no space for it to do so. The resulting forces are sufficient to burst the container. To prevent containers from being overcharged, regulations governing the storage of compressed gases specify how many kilograms may be charged into a container for every litre of container volume. This charge factor multiplied by the internal volume gives the permissible charge quantity. The charge factor for the refrigerants used in cars is 1.15 kg/l.
   

    Questions & answers

    Charge factor — Volkswagen Golf Mk7

    What is the charge factor for R134a containers?
    Containers must not be completely filled with liquid — space must be left for vapour expansion as temperature rises. The manual specifies safe fill ratios.
    Water content
    Only very small amounts of water are soluble in liquid refrigerant. On the other hand, refrigerant vapour and water vapour mix in any proportion. ...

    Detecting leaks
    External damage can cause leaks in the refrigerant circuit. Because a small leak will involve only small quantities of refrigerant, leaks should be checked for using an electronic leak detector or ...