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Volkswagen Golf Mk7 Service & Repair Manual: Pressure and boiling point

This page explains why Volkswagen Golf Mk7 refrigerant boiling points in reference tables are always based on 1 bar atmospheric pressure — changing the pressure on a liquid changes its boiling point correspondingly.

The boiling points given in the table below are always based on an atmospheric pressure of 1 bar. If the pressure on a liquid is changed, its boiling point changes also.
It is well known that, for example, the lower the pressure, the lower the temperature at which water boils.
The vapour pressure curves for water and for refrigerant R134a show that at constant pressure and falling temperature the vapour becomes liquid (in the condenser), and that when pressure drops, the refrigerant changes from liquid into the vapour state (evaporator).
   
Vapour pressure curve for water
A -  Liquid
B -  Gaseous
C -  Vapour pressure curve for water
1 -  Pressure on the liquid in bar (absolute)
2 -  Temperature in °C
 

Pressure and boiling point

Vapour pressure curve for refrigerant R134a
A -  Liquid
B -  Gaseous
D -  Vapour pressure curve for refrigerant R134a
1 -  Pressure on the liquid in bar (absolute)
2 -  Temperature in °C
 

Pressure and boiling point

    Questions & answers

    Pressure and boiling point — Volkswagen Golf Mk7

    How does pressure affect the Golf Mk7 AC refrigerant?
    Higher pressure raises the boiling point; lower pressure lowers it. The AC system uses this principle to make the refrigerant evaporate (absorb heat) and condense (release heat) at controlled temperatures.
    Heat always flows from warmer to colder material
    Every material consists of a mass of moving molecules. The fast moving molecules of a warmer material loose part of their energy to slower molecules possessing less heat. This slows down the molec ...

    Vapour pressure table for refrigerant R134a
    The vapour pressure table for each refrigerant is published in the literature for refrigeration engineers. This table shows the vapour pressure exerted on the liquid ...